Hamlet’s 4th Soliloquy Analyze

Hamlet’s 4th soliloquy analyze â€Å"To be or not to be† can arguably be Shakespeare’s most recognizable quote in all of his work. Hamlet attempts to reason with himself on whether or not death is the only solution to end all life suffering portrays him as both confused and cowardly. In this monologue, Hamlet goes into a tough debate over whether he should end his own suffering by commit suicide, or to step it up and revenge for his father. This solilguy also shows the reader on how Hamlet deals with stress and the lost of love one. In conclusion, he decided to live and fulfill his promise. Indication from this monologue exposed Hamlet’s flaws for lacking of action, being hesitant, and unable to settle his mind. This help lay the foundation of Hamlet’s characteristic and his reasons behind his actions in the later part of the play. Like many Shakespeare’s writing, it is up to the reader to decide on the characteristic of Hamlet. Many may view â€Å"to be or not to be† as Hamlet’s suicide attempt, however, it really portrays Hamlet as a stressed out young man that can not deal with his surrounding. Hamlet position himself between the two extremes with life and death by questioning himself on â€Å"†Whether 'tis nobler in the mind to suffer the slings and arrows of outrageous fortune or to take arms against a sea of troubles, And by opposing end them†. He asked himself if it is â€Å"nobler† to commit suicide, but quickly goes against his early statement by saying actions requires â€Å"arms against a sea of troubles†. This shows that Hamlet is puzzled with himself on whether he should end his â€Å"sea of troubles† by means of death, or to suffer through the pain of living. As Hamlet thinks towards death and ending all life stress, he quoted: â€Å"To die-to sleep, No more; and by a sleep to say we end The heart ache and the thousand natural shocks That flesh is heir to :’to consummation devoutly to be wished. To die, to sleep; To sleep, perchance to dream†. Hamlet wishes if he was dead, he will no longer have to suffer through his â€Å"heart-ache† and â€Å"thousand natural shocks†. The monologue continues as Hamlet debate on his decisions. Finally, Hamlet points out the reason why he choice to live instead of death. He choice to live because â€Å"the dread of something after death, The undiscover'd country from whose bourn No traveller returns, puzzles the will†. In other words, Hamlet unwilling to commit suicide is because he does not know what lies after death and it was against his religious believe. Ironically, through out the soliloquy, the reader can conclude from Hamlet’s sorrow and depression that he himself knows his weakness in thinking too much on his revenge and yet Hamlet does not react or even tries to. It has been weeks before Hamlet’s promises towards his father on revenge to kill Cladius, but once again, we see Hamlet is confused as ever. He then quotes: â€Å"Thus conscience does make cowards of us all; And thus the native hue of resolution Is sicklied o'er with the pale cast of thought, And enterprises of great pith and moment With this regard their currents turn awry, And lose the name of action†. This further fortifies the above statement for stating himself for being cowardly and did not take action when he had the chance. It seems that Hamlet needs to list out every possible outcome of his action before processing it. Hamlet is helpless of his own lack of confidence and this will lead to his ultimate doom. This important soliloquy exposed the flaws of Hamlet’s character and it shows Hamlet’s self conflict and his possible solutions in taking action. This is the main point of the play as it signifies a development in Hamlet’s thought and his readiness in finally starting to act. It also shows Hamlet’s approach on the question of life and death and how he compares both of them by over examine each and every possible outcome. This soliloquy also shows Hamlet’s puzzlement, lack of action and his overall cowardly behavior. We knows that Hamlet’s unwilling to commit suicide is because he wants revenge, but the more important question is whether revenge is truly keeping him alive, or that he is just too cowardly to face the mystery after death.

Implications of Day Care in Young Children Essay

Within this assignment I will be discussing the implications of day care for young children and giving both the positive and the negative aspects of this. A study was done in the united states by Kagen (1978), the study was done on children whose mothers worked, in which case the children were put into day care centres compared to home –reared children. Kagen found little difference between the children placed in day care centres and those raised at home either in the amount of protest or seeking closeness to their mothers when upset. From the findings it appears that it doesn’t matter if a child is in day-care or raised at home or the amount of hours spent with its mothers, there is a special bond between mother and child. Bee (1974) Concluded that there are no negative effects when a child is cared for in a day care centre, provided these are run by trained professionals and only a small number of children. However, Bee (1997) also suggests â€Å"The crucial issue is the discrepancy between the level of stimulation that the child would receive at home and the quality of day care. When the day care setting for the child provides more enrichment than the child would normally receive at home, we see some beneficial cognitive effects. When day care is less stimulating than the child’s home care would have been, it has negative effects.† Psychologists disagree about the developmental effects of day care on young children. Some agree with Bowlby’s prediction that long to medium term separation from the mother could have far-reaching consequences. Others claim that, provided day care is high quality day care has no adverse effects on intellectual development and does not disrupt the child’s attachments. Some psychologists believe that it might even make a positive contribution to the child’s development. The type and quality of care can influence many aspects of development—including memory, language development, school readiness, math and reading achievement, the nature of relationships with parents and teachers, social skills, work habits, and behavioural adjustments Below I have tried to outline the positive and negative aspects of day care: – Positives * When children attend nursery or playschool it’s clear that peer relationships take on increasing importance but peer relationship importance  is important before this . Early as 6 months old babies smile and are more vocal to other infants. * Intellectual stimulation * Helps develop some social skills- building relationship with peers and other trusted adults other than those within the family. * Psychologists have shown there is no affect on the mother-child attachment * Children receive Adequate and nutritious meals Negatives * Putting a child into day care can cause the child stress ( i.e upset from being away from its mother)as can any situation in which the mother isn’t with the child. * If a day care doesn’t have the correct form of attachment for adults and the children as mentioned above ( conclusion raised by Barbara Tizard) this will not have as greater benefits as a quality day care that has this attachment and familiarity etc. * Some research in the US argue that day care can cause the child to grow up to be aggressive and disruptive once they reach school age (research taken from -NICHD national child care study)

African Instruments

The history of African musical instruments is rich and diverse as the people that populate the African continent. Because music Is so deeply rooted in African culture, knowing about African instruments helps you understand the continent as well as the people. Apart from Africans themselves, this knowledge Is usually restricted to ethnomusicology and historians. The roots of African-American Instruments are burled deep within the music of the African continent. The history and evolution of African-Americans instruments are as rich and complex as the history of AfricanAmericans themselves. The essence of African-American Instruments Lies In Its expression of the human experience. Although the different styles vary widely In their tone, topic and the tools used to produce them, African-American Instruments have the ability to cross all color and culture lines. Styles such as the blues, country, jazz, gospel and hip hop have spread their Influence all over the world. Drums, banjo, and shakers have been a important key to making beautiful, inspiring music. Drumming was an important part of many African musical and religious radiation.The drum heads at either end of the drums wooden body are made from hide, fish-skin or other membranes which are wrapped around a wooden hoop. Leather cords or thongs run the length of the drums body and are wrapped around both hoops; when you squeeze these cords under your arm, the drum heads tighten, changing the instruments pitch. Drums served as an early form of long distance communication, and were used during ceremonial and religious functions. Ceremonial functions could include dance, rituals, story-telling and communication of points of order.The traditional drumming found in Africa is actually of three different types. Firstly, a rhythm can represent an idea (or signal). Secondly it can repeat the profile of a spoken utterance or thirdly it can simply be subject to musical laws. Drum Communication were based on actual natural languages. The sounds produced are conventionalism or idiomatic signals based on speech patterns. The messages are normally very stereotyped and context-dependent. By playing the drums the slaves would send warnings such as, the king is approaching or the enemy is attacking.After the work day was over, slaves would get together and sing out affirmations, pledges and prayers that they eventually lengthened out with repetitive choruses. At first, they accompany their vocals with handmade drums, but slave owners soon grew worrisome that this may be some sort of signal being made from one set of slaves to another that would ultimately lead to a revolt so the use of drums was abolished. African Instruments By Serenading populate the African continent. Because music is so deeply rooted in African culture, the people.Apart from Africans themselves, this knowledge is usually restricted to ethnomusicology and historians. The roots of African-American instruments are buried deep within the music of the African continent. The history and evolution of Americans themselves. The essence of African-American instruments lies in its expression of the human experience. Although the different styles vary widely in their tone, topic and the tools used to produce them, African-American instruments jazz, gospel and hip hop have spread their influence all over the world.

Managing International Business Enterprises Essay

Managing International Business Enterprises - Essay Example According to Wooten (2011) marketing managers need to effectively communicate the unique linguistic preferences up front to the translation companies so that the translation does not dilute the brand. The important thing in translation is to retain the original key brand message and tone as closely as is possible. The article proposes that companies need to work with professional linguistic translators whose native language is the target language. This article’s key message is concise and well-illustrated. Maintaining a brand’s image and meaning once a company decides to go global is both a product management and promotional strategy issue. Central to this move into the international market is the role of marketing managers. Marketing managers need to closely work with language service providers so as to effectively convey their brand messages. This will also call for flexibility and foresight since the translated names should also cater for brand growth. An example o f this is Coca-Cola’s translation â€Å"K’o K’ou K’o Le† was coined several decades ago yet its literal meaning â€Å"happiness in the mouth† is very much applicable to its present day â€Å"Open Happiness† campaign.

The Economy, Monetary Policy and Monopolies Essay

The Economy, Monetary Policy and Monopolies - Essay Example For instance, in 2007 the interest rate was recorded to be approximately 5% which decreased to below 1% by the end of 2009. Since then, till the current phase of the economic conditions prevailing within United States the interest rates has been recorded below 0.5% which shows further decline in the country’s financial market (US Department of the Treasury, 2012). Inflation Rates Fig.2: US Inflation Rates 2002-2012 (US Inflation Calculator, 2012) The inflation rates of the United States which was recorded as 4.1% during the year 2007 which further declined to 0.1% by the year 2008. However, it augmented to an average of 2% within the period of 2009 to 2012. This indicates that in terms of inflation rates the economy is regaining its stability performing almost similarly as during the period prior to 2007 (US Inflation Calculator, 2012). Unemployment Rates Fig.3: US Unemployment Rates 2007-2012 (U.S. Bureau of Labor Statistics, 2012) In relation to the above represented statist ics, it can be observed that United States witnessed an unemployment rate between 4-5% during 2007-2008. This further augmented to above 8% by 2012. This indicates that the economy had been witnessing a continuous de-gradation of its employment situation in the labor market over the past five years (U.S. Bureau of Labor Statistics, 2012). 2. Propose two (2) strategies that the federal government could implement that would encourage people to spend more money in order to create employment opportunities. Financial Leverage Financial leverage can be considered as one of the effective sets of practices in which the Return on Equity (RoE) is increased through the escalating rate of debt amounts. With this concern, the federal government of the U.S. should be focused on magnifying the amount of RoE even in situations when debt amounts tend to be increasing. Therefore, the financial strategy of the federal government should consider the investable assets related to the amount of equity as it would promote financial growth (Financial Literacy and Education Commission, 2011). Financial Decision Making and Financial Literacy Strategies related to the augmentation of financial literacy and effective decision making process would further provide competent direction in relation to financial education, policy, research, practice as well as coordination among the stakeholders, investors and other financial institutions. Moreover, effective forms of financial education and decision making process would offer the benefits of evaluating the risk of interest rates and provide an effective way to trim down the debt amounts (Financial Literacy and Education Commission, 2011). 3. Identify a situation in the past 50 years in which the government used antitrust policies to stop a monopoly from occurring. Include the circumstances of the proposed monopoly and the reason the government stepped in. Predict what would have occurred had the monopoly succeeded. Various antitrust policies h ave been implemented by the US government over the past decades to prohibit unhealthy competition in terms of monopoly within its national business environment. One of such Act can be identified as the National Cooperative Research Act of 1984 (15 U.S.C. Â § Â § 4301-05). The reason behind implementing this act can be

History Assignment Example | Topics and Well Written Essays - 500 words - 1

History - Assignment Example The Palestinian partisans were funded and backed by the Arab neighbors. On May 1967, Nassar (Egypt's President) had the UN withdraw from Egypt. He then sent tanks and troops into the Sinai. Israel responded by moving troops as well. On June 5, 1967 Israel attacked the Egyptian air forces. With Israeli air planes protecting their troops and tanks, they easily took the Sinai. If the UN would not have stopped the war, Israel would have gone further into Egyptian territory. Israel also captured Jerusalem and Golan Heights during this war. Israel won the Six Day War. The Yom Kippur War led to Syria and Egypt to attack Israel again. This time after battles and negotiations, Israel gave back the Sinai and parts of other territory taken in the Six Day War. However this war lead to the Camp David Accords and led to Egypt recognizing Israel as a state. I.D. the following terms in paragraph format. Make sure you include ALL INFORMATION from the book: Do NOT just copy from the book. You must put these in your own words. (worth 5 points each) 1. Palestinian refugees Palestinian refugees are Arabs caught on Israeli land or in the Occupied Territories after the wars between Israel and their Arab neighbors. These individuals are waiting to be given citizenship by Israel or liberated by the country Israel took the land from.

Internet Marketing Essay Example | Topics and Well Written Essays - 1500 words - 1

Internet Marketing - Essay Example Online marketing may refer to all kinds of marketing done on the company website, emails written to customers and other wireless media. Customer relationship can earn a company competitive edge since good relationships build trust and, hence, regular customers. Internet marketing binds together the art of creativity and technical elements of the Internet comprising design, development, public relations, and sales. Internet marketing is mostly done through the company website and social sites like Facebook and Twitter (Maughan, 2007:58). Although the main goal of the internet marketing is to grow the company business, the company should emphasize winning customer trust by appearing genuine and promising what it can offer. This is because internet influences chances of frauds; hence, imposters can steal from customers. Zappo embraces internet marketing to sell its products, which are majorly shoes and bags. Use of the Internet to market its products is of high importance as the company encourages all employees to exploit social media networks and connect with customers following the companies’ core values. This has endowed Zappo with great support since the employees are active on Twitter, the company’s director being most popular. Zappo uses YouTube to display its products, give speeches to customers through videos, which majorly highlight company values, customer feedback and compliments. Facebook is one of its engines towards customer feedback and discussions that present an opportunity to clear doubts and instill confidence and trust. Zappo has several blogs giving information on its products, employees, and management. Blogging creates credibility and wide readership and enables customers to understand the company better as well as reduce fears. A company aspiring to succeed in online marketing should invest in a good-looking design (Rosen,

Dreams and Cinema Assignment Example | Topics and Well Written Essays - 2000 words

Dreams and Cinema - Assignment Example Many reasons why cinema was based on dreams were psychological. Theorists researched through psychology, sociology, and aesthetics to conclude that the dream metaphor has been used relevantly in cinema and has been established as the most important contribution in film theory. Dreams and films are both considered to be perceived objectively by the spectators and dreamers. Just as in dreams, in films as well we do not perceive the real presence of the people and situations. However, there are two characteristics which may separate films from dreams; and these are materiality and presence of the original physical object. This difference is not a major one when considering the use of dreams sequences in films with special lighting and sound effects. Freud’s theories have grounded the relationship between dreams and films. He was the best psychoanalyst who believed that dreams are the major source of all ideas. All dreams must have a visual representation which is the dramatizatio n or the representation of the dream thoughts through visual situations. Even though Freud never mentioned the use of film or cinema as the representation of dreams, his ideas about the dream thoughts closely relate to the visual film language. In addition to the views of Freud about visual representation of dreams, there were many other psychoanalysts who talked about the relevant consideration of the visual language of dreams. Jung, another psychoanalyst, suggested that dreams are developed based on a dramatic structure.

Real estate economics Assignment Example | Topics and Well Written Essays - 2500 words

Real estate economics - Assignment Example This layout perceives a city as a pattern of settlement, which can be described using concentric regions. In this case, the epicentre represents the Central Business District (CBD). Here, any economic activity is highly regarded since the market is accessible to all. In order to understand the monocentric models, four primary factors are considered. They include; the fact that, the CBD acts as the core area of activities, where transport lines are connected to (Lin, 2014). Secondly, the people living in the CBD live in other cities, which surround the CBD, thus have to commute on a daily basis to the CBD. The third characteristic is the intercity transportation, where the goods obtained from the CBD are ferried to other cities, through common means of transport, such as rail and roads. Since the people here are in constant business, they exchange ideas and participate in a given trend of activities. As a result, they develop a culture, which further stratifies the layout of the monoc entric city. Here, the forms of settlement are stratified and distinctively isolated to a given economic class. The land rates are expected to be highest in the CBD and reduce outwards. Here, the main occupants of the CBD include businesses and offices. These groups of tenants are willing to pay high rent, since they seek to position themselves strategically, in order to access the customers’ strategic locations (Hanushek, 2014). In this research, the area selected is Manchester city, with all the cities around it. They include Oldham, Rockdale, Salford, Stockport, Tameside, Trafford and Wigan. The choice was based on the economic significance of the cities. In addition, the density of settlements and the accessibility of the areas. Then, the researcher opted to concentrate on the rateable values and area of the rented space (Madariaga, 2014). The combination of the two parameters

Prospectus Essay Example | Topics and Well Written Essays - 250 words - 1

Prospectus - Essay Example The social ethics and morals should also be a considered in coming up with a stand on abortion. In my research I want to provide ethical reasoning to support my stand against abortion. In my research paper I will us the ethical standards that shape the society. Additionally, I will borrow heavily from the ethical and morality requirements from the bible. I will relate abortion to the biblical definition of murder. The main areas in my research paper will be why abortion should be illegal, the alternatives to abortion and the social and biblical approach when dealing with abortion. In this publication the author is strongly against abortion and she termed it as the worst case of murder in the society. According to Naden it is against the society and biblical norms to carry out an abortion (95). In Bacon’s words, abortion should not be treated as a way by which women are satisfied and taken care of. The author further argues that perpetrators of abortion should be prosecuted and charged with murder (68). The arguments by Libby revolve around ethical and moral issues related to abortion. The author argues that a child should be born even in the most complicated was so long as the existence of the mother is not jeopardized (113). Hunt argues that abortion is a shortcut by which individuals use to avoid responsibility (98). In an ethical and moral way, parents should be accountable for their own deeds. The author also uses biblical theories to support his stand against

Three Main Problems in the Middle East Essay Example for Free

Three Main Problems in the Middle East Essay The Middle East, as the West calls the Islamic region in Southwestern Asian continent, had been the focus of many recent studies. The region’s key role in shaping global economy and politics could be the main reasons why the Middle East became so intriguing within the circles of academic debates, political policies and other similar venues. News from this region usually carries banner stories of suicide bombings, wars, terrorism and similarly outrageous reportage.   Thus, Middle East was portrayed to the public as land or chaos, tyranny and intricate conspiracies and violence. Although the Middle East has a rich history of its people, culture and political sovereignty, it had long been disregarded especially that the focus of most historiography and social sciences are on the Western civilizations. . Throughout the course of societal evolutions, the Middle East had always been portrayed as the villain and the West so often portrayed as the arbiter and the good guys in wars and other social turmoil that happened in the region for the past centuries. Despite numerous attempts to deeply probe into the secrets of the region, the Islamic world had always been subjected to the probing eyes of the global community. It had long been misunderstood, maybe because of ignorance to the real situation in the Middle East that, that this part of the world is ‘no man’s land’ because of terrorism and tyrants which the Western powers so despise.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Hence, the dilemma that world faces regarding the situation in the Middle East is a problem caused by ignorance of the historical background which had molded the region’s economic, political and cultural dynamism. On the outside it could be viewed as a static block of nation-states, firmly anchored on Islamist fanaticism but much like any other country, the people are waging a struggle in various ways possible to change the existing order. This paper aims to break the notion that the Islamic Middle East is a rigid desert of ideological uniformity (Beinin Stork 7). Often that terrorism was linked to Islamic doctrines since the United States waged its global war on terror. Arbitrarily, the policies that sought to counter terrorism were not really directed to the ultimate cessation     of terrorism as a tool for anarchic ends but were effectively used to control the economic and political life of the countries in this region. It was effectively manipulated that from the true circumspection of terrorist movements the attention was diverted to superficial issues that were less likely to resolve the conflict, both external and internal.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   The lack of unity of the Middle Eastern nations can be viewed as one of the reasons why this region is continually deprived of West-defined peace and stability. One possible answer is that Western powers have greatly profited from the absence of a uniting factor among Muslim neighbors. Though almost all of these Muslim nations had laws and forms of government highly adhesive to religious thought, there were still varied interpretations in the context of ‘religious’ approaches to state affairs, not to   mention the sectarian divisions within Islam. Take Iran and Iraq for example. Although there were reasons for the war between these two nations in 1980’s, the sectarian differences of the two nations have greatly affected the course of the war for domination of the Persian Gulf (Moghadam 136-138). The Islamic nations were divided by certain issues that had created a vast misunderstanding among themselves. The dilemma brought by secularist ideas caused the rifts between and among governments to worsen. Islam was at the very first of this dilemma. Its nature had long been argued, whether it is a religion or a civilization. The answer to this question however is not on the religious aspect itself but on the political side of the. Islam’s definition is a matter of political refinement that was effectively sown to disarray the focus of scholars in finding the answer to the question of why Islamic militancy, radicalism and fundamentalism (Filali-Ansary 196-197).   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   In the centuries that have passed, nationalism was developed in the Middle East due to external threats, especially those that was posed by Western colonial powers. Nationalism in other nations such as Turkey and Iran went far beyond the limits of nationhood. At some point during Mustafa Kemal Ataturk and Shah Pahlavi’s reign, touched even the religious aspect of the nation such that they even used military force to impose a â€Å"Western† concept of nationhood, one which is secular (Hashemi 168). However, through the decades, Islamic modernism had been witnessed which broadened the spectrum for political commonality. These types of deviation from the Islamic codification and norms among Islamic societies were the start of a somewhat â€Å"betrayal† of the Islamic chord.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Those countries that have embraced westernization were isolated from the Islamic fundamentalist section of the Muslim nations. Such embrace of the infidel’s culture was to them a desecration of the Islamic customs. If history will be reviewed this divisions were more of cultural in essence. For hundreds of years, the Islamic states turn against each other for subjugation. The Ottomans annexed Egypt and many other nations in the Mediterranean belt. This display of hostility towards each other became vital in the ferment of suspicion between each nation (Moaddel 128-129). The dilemma of the forming a single political force cannot be only be blamed on the religious aspects of the society but also of foreign control and domination. The vast oilfields of the region had been enticing for Western powers so that they supported some regimes and made use of tactical alliances during the Soviet annexation of Afghanistan in the 80’s. The House of Saud of Saudi Arabia for example had strong ties to European regimes since many of these regimes have economic interests in the region (Beinin Stork 4).   This had been aggravated by the current developments in world politics directly concerning the region. The terror hysteria and the subsequent wars thereafter grappled Afghanistan and Iraq further divided the Islamic world. Regimes friendly to the United States were caught in the middle of the squabble. George W. Bush’s pronouncements in the onset of the war on terror forced these regimes to support the anti-terror war lest they would be ‘with the terrorists.’ Such actions were explicitly influential in the polarization of the Middle East. Samuel Huntington was quoted on the exact description of the implications of this event: â€Å"On the other hand, the â€Å"clash of civilizations† thesis resurfaces and reverberates. Even though many refused Samuel Huntington’s thesis for its simplistic and essentialist depiction of cultures and cultural interaction, his conceptual framework proved its resilience, particularly with the September 11, 2001 terrorist attacks. Islam quickly became the inscrutable, violent, and intractable Other, a threat to liberal democratic values† (Arat 2). The rationale of the war on terror, as claimed by US propagandists, is aimed at the Islamic regimes was to promote democracy in the backward governments that are hospitable to or actually promotes terrorist organization. In countries wherein the regimes are somewhat committed to the liberal democratic ideology: â€Å"†¦some 250 million USD that USAID alone spent in the Arab world on projects and programs related to DP () certainly seems more than the negligible amount of money, this must be contrasted with the roughly one billion USD the United States appends each year in Egypt alone – on military aid for the Mubarak regime. Some observers have recently depicted the â€Å"forward strategy for freedom† in the Middle East announced by the Bush administration as a major shift from former US policies toward the region, emphasizing today the importance of democratic rule as opposed to†¦strategies based on the primacy of stability over democracy† (Schlumberger 37-38). The Middle East was an easy prey for US military campaigns primarily because of the forms of government that these nations have adopted. It was easy to claim in totalitarian regimes that these nations must be introduced to democracy and liberate the people from the clutches of Islamic dictatorships. Such was being used today in Iran in the face of nuclear weapons issue, Syria on its human rights records, and Libya on its anti-imperialist stance, while others have remained to be isolated from their people because of their failure to address the concerns of the citizens. A post- invasion Iraq have had experienced the resurgence of Islamic militancy and fundamentalism in the outset of a US-backed puppet regime. Such events even drove the conflict outside the borders of Iraq and spilled through Syria, Iran, and Egypt, only to name a few, in the name of aiding their Muslim brothers (Beinin Stork 7). It should be understood though that this politicization of Islam did not occur overnight. This could again be traced from the past centuries and decades of Western domination. The Crusades in the middle ages could even be the source of this politicization. But most notably, this politicization was most effectively utilized by the US against the Soviet Union in the 80’s during the Afghan war. After the Afghan war these radicalized freedom fighters were transformed into terrorist groups and from then on political Islam has been interchanged with fundamentalism, militant Islamic movements and the like to directly associate genuine liberation movements to terrorism and downplay the legitimate issues raised by these groups (Beinin Stork 5). Both served the US in ridding it of its enemies and protecting its allied regimes against internal liberation movements. The question now arises whether democracy would be possible in Islamic societies. Some do believe. It is said that these societies were torn into two governing laws. One of those is Islamic or the shari’a and the other, secular. There had been stressed points that states that these governments, though harboring the Islamic hierarchy of powers still consider a ‘consultative’ form of governing, thus a democratic interaction among the ruler and ruled (Filali-Ansary 200).   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   What is unique in the Middle East is that in order to reinstate the Islamic laws as the supreme judicial system is through revolution which has happened in Iran. Such was the perceptions in the Middle East that women, as a part of the revolutionary process, were restricted. However: â€Å"In Iran as of 1994, 30 percent of government employees were women, and 40 percent of university students were women, up from 12 percent in 1978. In the past few decades, women have thus made significant, but uneven, strides in the labor force†¦Hassan al-Turabi claims that women in Sudan â€Å"have played a more important role in the National Islamic Front than men recently† in all aspects of party, in Parliament, and as ministers and judges. Segregation is definitely not a part of Islam.[though his claims in Sudan are disputed]†¦it is clear that women elsewhere in the Muslim World –Morocco, Jordan, Egypt†¦Turkey – do hold political office† (Eickelmann and Piscatori 95) Within this basis one could assert initially that women are not bound to the patriarchal society, but in order to truly say that women have had complete freedom, would rest on the cultural and religious aspects of the society. But along with these concerns the forces of democratization have failed to touch the issues on gender. This issue in the Middle Eastern nations had been raising a movement by women who had, despite the conflicts that the patriarchal regimes fight, lack in total consideration of the women (Moghadam 139). Regimes may be considered as progressives in terms of political and economic stance but there is a difficulty in assessing whether theses same governments would consider the question on gender. Proving this may be difficult because of the religious aspect of the concern which all regimes, pro or anti-US, share. These seemingly centuries old threats to the Islamic societies from the outside caused by rifts within the regimes themselves had also been supplemented by internal difficulties which these regimes face (Dris-Ait-Hamadouche 117). Even though the states were divided by the political tensions developed by the combination of historical and contemporary Western influences, women in the Middle East are somewhat united in their fight for women’s right in the predominantly patriarchal culture of the Islamic nation. The issue of gender is completely intertwined with the issue of secularization (Nanes 113-115). Different governments were torn between allowing certain liberal manifestations of secular authority in public places and religious considerations (Najmabadi 240-241).   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Seemingly, the problems of the Middle East with regards to the political and cultural aspects are not to be considered as solitary and independent of the economy. The reason that Western powers are interested in the liberal democratic conception of regimes is because of the economic interests that US has with the resource rich desserts. The only conclusive message that these events relay to us is that these were all concocted in order to divide the Islamic world and extinguish its formidable force against foreign interests especially that of US. Islamic Middle East had long been captured in that policy cage and until the resources are there, the clutches of US hegemony in the Islamic world will never loosen. Works Cited Arat, Yesim. Rethinking Islam and Liberal Democracy: Islamist Women in Turkish Politics. New York: State University of New York Press, 2005. Beinin, Joel, and Joe Stork. On the Modernity, Historical Specificity, and International Context of Political Islam.   Political Islam: Essays from Middle East Report. Eds. Joel Beinin and Joe Stork. Los Angeles: University of California Press, 1997. Dris-Ait-Hamadouche, Louisa. Women in the Maghreb: Civil Societys Actors or Political Instruments? Middle East Policy 14.4 (2007). Eickelman, Dale F., and James Piscatori. The Firmest Ties and the Ties That Bind: The Politics of Family and Ethnicity.   Muslim Politics. New Jersey Filali-Ansary, Abdou. Muslims and Democracy.   Islam and Democracy in the Middle East. Eds. Larry Diamond, Marc F. Plattner and Daniel Brumberg. London: The John Hopkins University Press, 2003. Hashemi, Nader A. Islamic Fundamentalism and the Trauma of Modernization: Reflections on Religion and Radical Politics.   An Islamic Reformation? Eds. Michaelle Browers and Charles Kurzman. New York: Lexington Books. Moaddel, Mansoor. Islamic Modernism, Nationalism, and Fundamentalism: Episode and Discourse. Chicago: The University of Chicago Press. Moghadam, Valentine. A Tale of Two Countries: State, Society, and Gender Politics in Iran and Afghanistan. The Muslim World 94.October 2004 (2004). Moghadam, Valentine. Patriarchy in Transition: Women and the Changing Family in the Middle East. Journal of Comparative Family Studies 35.2 (2004): 137. Najmabadi, Afsaneh. Gender and Secularismhow Can a Muslim Woman Be French? Feminist Studies 32.2 (2006): 239. Nanes, Stefanie Eileen. Fighting Honor Crimes: Evidence of Civil Society in Jordan. The Middle East Journal 57.1 (2003). Schlumberger, Oliver. Dancing with Wolves: Dillemas of Democracy Promotion in Authoritarian Context.   Democratization and Development: New Political Strategies for the Middle East. Ed. Dietrich Jung. New York: Palgrave Macmillan, 2006. Princeton University Press, 1996.

Trends in Human Services Essay Example for Free

Trends in Human Services Essay To run an organization, the management of the labor plays a great role in reflecting on the output of the company.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   In the recent years, there are challenges due to technological, economic changes, competition and market trends. An organizations needs to cater for the needs of employees and ensure friendly supervision as well as freedom to the employees. To ensure high performance , this will involve attracting, developing and retaining a qualified and motivated workforce. The top management foresees the needs of their employees and organizes for training and development sessions among others. The personal needs of the employees are taken care; they are involved in decision making and participate in organization’s activities. Developing of the employees’ potential is very critical so that there is self actualization through job sharing, job enlargement and job-enriching. An action plan is prepared so that recruiting, selecting, training and developing and rewarding of employees is recognized and done properly. Continued efforts at work between the management and staff helps to achieve organizational success locally and internationally through legal compliance and employee satisfaction.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   For high output, strategic management will aim to integrate the managerial planning and decision making and hence lead to forecasting, planning and acquisition of desired labor force. There are programs that ensure right number of individuals is available at the right place and right time, and this ensures effective running of an organization. Delays may be felt when fewer labor force is recruited while a high number would lead to labor wastage and incurred loses.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   A lengthy procedure that recruits and selects applicants ultimately identifies and selects prospective employees. While carrying out the interview, actual screening and selection of appropriate candidates require good planning, availability of resources and qualified interviewers. For fair approval, discrimination of the candidates due to gender, age or nationality should be avoided.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   A safe and healthy working environment is a requirement by virtue of legal, social and political value especially due to exposure to hazardous substances or stress in the workplace. Safety equipment as well as accident prevention programs have been put forward to ensure safer environments.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   As a result of the competitive global economy, managing labors relations have been great concern especially because the economy is service oriented. There is need to prioritize the needs of the organization and that of the employees and constructively analyzed and take them into consideration.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   The quality of some services offered may have negative environmental and human health effects and this has been felt in some social groups due to poverty in such regions. The well being of many people has been improved while others have been affected by the international trade. Competition for same resources may occur however this should be constructively managed so that one group does not benefit at the expense of the other.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   A great benefit in conserving the various groups is to inform the society to explicitly consider trade-offs between different regions and people as well as the labor force because this benefits the society.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   To help the organization’s ability in service delivery, selection of the human resource especially is crucial. For example, those coming from a relatively poor region need the support of the management so as to increase their output.   Technology has ensured continued identification, monitoring and reviewing of the services specified. Use of computer rather that manual operations has improved the quality and accuracy in the service delivered. The difference in biodiversity has not affected these operations and hence technology has offset the cost of service delivery.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Over dependence on government funding or sponsorship while carrying out projects in regional areas may be frustrated as a result of extra costs in some regions of a country. Where the government sets out the priorities for investments in a certain year, the funds may not have been adequately allocated and hence may affect service delivery. Reference: Marianne w., Tricia M. (2006) Introduction To Human Services:

Characterizing Novel Methoxybenzene via Boron-ate Complex

Characterizing Novel Methoxybenzene via Boron-ate Complex Synthesis and Characterization of Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene via Boron-ate Complex Habib Hussain[*], Syeda Rubina Gilani, Zulfiqar Ali, Imdad Hussain, Hajira Rehman   Abstract: Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene was synthesized through boron-ate complex. 3-(4-methoxyphenyl)propyl diisopropylcarbamate was reacted with allylboronic acid pinacol ester in the presence of N,N,N,N-tetramethylethyllenediamine (TMEDA) to give secondary boronic ester which was further reacted with (vinylsulfonyl)benzene by using Grubbs Hoveyda II. Resulting product (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane was then treated with 1-bromo-3,5-bis(trifluoromethyl)benzene in the presence of n-BuLi to get nucleophilic boron-ate complex. (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene was obtained in excellent yields by stirring boron-ate complex at 50oC for 1h and refluxing for 15h. Keywords: Lithiation Borylation, Secondary Boronic Ester, Olefin Cross Metathesis, 1-bromo-3,5-bis(trifluoromethyl)benzene , Boron-ate Complex 1. Introduction Olefin metathesis chemistry1 has led a number of opportunities in organic synthesis. Olefin metathesis2involves the redistribution of fragments ofalkenes by regeneration of carbon-carbondouble bonds. There are numerous applications of olefin metathesis and it is an important methodology to produce reagents. Addition of aryl lithium reagents to secondary boronic esters results to a new class of chiral organometallic-type reagents which have broad utility in asymmetric organic synthesis. R. Larouche-Gauthier3 formed intermediate boron-ate complex by adding an aryllithium reagent to a secondary boronic ester. It behaved as a chiral nucleophile and maximum enantioselectivity was found by using electron withdrawing groups on aryllithium. Habib Hussain4 studied the effect of steric bulk of aryllithium on stereoselectivity of boron-ate complexes. Hoffmann5 obtained chiral Grignard reagents from sulfoxides Mg exchange reaction of halosulfoxides. Herbert C. Brown6 investigated iodination of the ate- complexes from various B-alkoxyborinane derivatives and 1-alkynyllithium. E. Vedejs7 synthesized ate- complexes which contained stereogenic boron by reacting trivalent boranes with nucleophiles. They noticed that stability of ate-complex depend upon the electronegativity of substituents attached to b oron. Ryschkewitsch, G. E8 resolved chiral boron-ate complexes by classical methods. Anna Bernardi 9 determined the role of ate-complxes im aldol stereoselectivity. In the recent paper, we reported the synthesis of Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene (7). It was characterized by IR, 1H, 13C and ms. Lithiation-Borylation was used to synthesize the secondary boronic ester and by using olefin cross metathesis, it gave (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane when reacted with (vinylsulfonyl)benzene. (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane was converted into ate-complex when on heating produced the desired product. 2. Experimental Section 2.1. Materials: n-butyllithium (nBuLi), sec. butyllithium solution (sBuLi) (1.6M), pinacol, N,N,N,N-tetramethylethyllenediamine (TMEDA), (vinylsulfonyl)benzene, Grubbs Hoveyda II and 1-bromo-3,5-bis(trifluoromethyl)benzene were purchased from Sigma Aldrich. All reagents were used as such as received. To avoid from moisture diethyl ether (Et2O) and tetrahydrofuran (THF) were dried with 4 A ° molecular sieves. The experiments were performed using schlenk line under nitrogen atmosphere in the absence of air and moisture. 2.2. Synthesis and Characterization of 2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3): To a solution of 3-(4-methoxyphenyl)propyl diisopropylcarbamate (1.0g, 3.41mmol, 1.0eq) (1) and N,N,N,N-tetramethylethyllenediamine (TMEDA) (0.61mL, 4.09mmol, 1.2eq) (2a) in Et2O (17mL) at -78oC, Sec. BuLi (1.6M in 92:8 cyclohexane/hexane, 2.9mL, 3.75mmol, 1.1eq) was dropwise added and stirred for 5h at -78oC. Then allylboronic acid pinacol ester (0.77mL, 4.09mmol, 1.2eq) (2) was dropwise added to the reaction mixture and further stirred at -78oC for 1h and allowed to warm to room temperature. At this stage, a solution of MgBr2.OEt2 in Et2O, made as follows, was added to the reaction mixture. [At room temperature, 1,2-dibromoethane (0.60mL, 6.88mmol, 1.0eq) was added into a suspension of magnesium (0.17g, 6.88mmol, 1.0eq) in Et2O (8.6mL). The reaction flask was further stirred for 2h after placing into a water bath in order to control the moderate exotherm]. Biphasic mixture having two layers thus obtained was added to the former reaction mixture via syringe and then refluxed for 16h . After cooling the reaction mixture to room temperature it was quenched with water. Et2O was added, the layers were separated and the aqueous phase was extracted with Et2O. The combined organic layers were washed with 1N HCl, 1N NaOH, water and brine, dried (MgSO4), concentrated and purified by column chromatography (SiO2) and pure (R)-2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3) (0.84g, 77.60%) was obtained as colorless oil. The reaction is given in Figure 1. 1H NMR (400 MHz, CDCl3) ÃŽ ´ ppm 7.09 (2H, d, J=8.80 Hz, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.81 (2H, d, J=8.80 Hz, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 5.86 – 5.75 (1H, m, CH=CH2) 5.04 (1H, d, J=2.20 Hz, CH=CHH) 4.94 (1H, d, J=10.27 Hz, CH=CHH) 3.78 (3H, s, OCH3) 2.63 2.48 (2H, m, ArCH2CH2CHBCH2) 2.27 2.11 (2H, m, ArCH2CH2CHBCH2) 1.78 1.58 (2H, m, ArCH2CH2CHBCH2) 1.25 (12H, s, 4 à ¯Ã¢â‚¬Å¡Ã‚ ´ CH3) 1.08 1.18 (1H, m, ArCH2CH2CHBCH2) 13C NMR (100 MHz, CDCl3) ÃŽ ´ ppm 157.6 (1C, -OCH3), 138.4 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH), 135.0 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH), 129.2 (1C, ArC-O), 114.9 (1C, -CH2CH=CH2), 113.6 (1C, -CHb=CH2), 83.0 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ C(CH3)2), 55.2 (1C, ArCCH2), 35.3 (1C, CH2CH2CHB), 34.5 (1C, -CH2CHB), 33.1 (1C, -CHBCH2CH), 24.9 (1C, -CH2CH2CHB), 24.8 (4C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ (CH3)2C). 11B NMR (96.23 MHz, None) ÃŽ ´ ppm 33.24 IR (film): ÃŽ ½ (cm–1) 3026 (sp2C-H Stretch), 2977, 2924, 2852 (sp3 C-H Stretch), 1511, 1456(sp2 C=C Stretch), 1243, 1175, 1142 (sp3C-O Stretch), 846, 822, 670 (sp2 C-H oop bending). 2.3. Synthesis and Characterization of (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5): Grubbs-Hoveyda II (4a) (3.9mg, 0.0063mmol, 0.05eq) was added to a solution of 2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3) (40mg, 0.126 mmol, 1.0eq) and (vinylsulfonyl)benzene (4) (0.0635g, 0.378mmol, 3.0eq) in CH2Cl2 (2mL). After fitting a condenser to the flask, reaction mixture was refluxed for 15h under nitrogen. The reaction mixture was then reduced in volume to 0.5mL and purified directly on a silica gel column eluting with 9:1 Pet. Ether/ EtOAc to provide the desired product (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5) as dark brown solid (0.0438g, 77.25%)10. m.p. 82.0oC 1H NMR (400 MHz, CDCl3) ÃŽ ´ ppm 7.88-7.84 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 7.62-7.56 (1H, m, , 1 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 7.54-7.48 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 7.05-6.99 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.96 (1H, t, J=6.97 Hz, CH2-CH=CH) 6.84-6.77 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.31 (1H, dt, J=15.16, 1.47 Hz, CH2-CH=CH) 3.78 (3H, s, -CH3) 2.59-2.45 (2H, m, CH2-CH2-CHB) 2.43-2.26 (2H, m, CH2-CHB-CH2) 1.77-1.66 (1H, m, CH2-CHB-CHH) 1.63-1.53 (1H, m, CH2-CHB-CHH) 1.27-1.21 (1H, m, CH2-CHB-CH2) 1.18 (12 H, s, 4 à ¯Ã¢â‚¬Å¡Ã‚ ´ CH3) 13C NMR (100 MHz, CDCl3) ÃŽ ´ ppm 157.7 (1C, ArC-O) 146.9 (1C, ArC-S) 140.8 (1C, CH=CH-S) 134.2 (1C, CH=CH-S) 133.1 (1C, ArC-CH2) 130.6 (1C, ArCH) 129.2 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 129.1 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 127.5 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 113.7 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 83.4 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ C(CH3)2) 55.2 (1C, OCH3) 34.1 (1C, CH2CHBCH2) 33.1 (1C, CH2CH2CHB) 32.8 (4C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ (CH3)2C) 24.8 (1C, -CHBCH2CH) 24.7 (1C, CH2CH2CHB) 11B NMR (96.23 MHz, None) ÃŽ ´ ppm 33.24 IR (film): ÃŽ ½ (cm–1) 2977, 2924 (sp3 C-H Stretch), 1511, 1446(sp2 C=C Stretch), 1244, 1176, 1141 (sp3C-O Stretch), 822, 730, 687 (sp2 C-H oop bending). 2.4. Synthesis and Characterization of (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene (7): To a solution of 3,5-(CF3)2C6H3Br (24.6mg, 0.084mmol, 1.2eq) in THF (1.9mL) at -78oC was added n-BuLi (1.6M in hexanes, 0.053mL, 0.084mmol, 1.2eq) dropwise. The mixture was stirred for 1 hr at -78oC before a solution of boronic ester (32mg, 0.070mmol, 1.0eq) in THF (1.5mL) was added dropwise. The reaction mixture was stirred for 30min at -78oC and 30min at room temperature to form boron-ate complex which was further heated at 50oC for 1 hr and refluxed for 15hr. Reaction was quenched with water, EtOAc was added and layers were separated. The aqueous phase was extracted with EtOAc. Then layers were combined, washed with brine, dried (MgSO4), concentrated. The crude mixture was finally purified by column chromatography (SiO2, 2:1 Pet.Ether/EtOAc) to get desired product as colorless oil (19.87mg, 62.10%). 1H NMR (400 MHz, CDCl3) ÃŽ ´ ppm 7.14-7.07 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.85 6.80 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.30 (1H, dt, J=17.00, 10.21 Hz, CH=CH-CH=CH2) 6.12-5.97 (1H, m, CH=CH-CH=CH2) 5.78-5.69 (1H, m, CH=CH-CH=CH2) 5.21-5.06 (1H, m, CH=CHH) 4.99-4.95 (1H, m, CH=CHH) 3.79 (3H, s, -CH3) 2.70-2.60 (2H, m, CH2CH2CH) 2.52-2.33 (2H, m, CH2CH2CH) 13C NMR (100 MHz, CDCl3) ÃŽ ´ ppm 157.7 (1C, ArC-O) 137.0 (1C, CH=CH2) 133.7 (1C, CH=CH-CH=CH2) 132.0 (1C, ArC-CH2) 129.5 (1C, CH=CH-CH=CH2) 129.1 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 114.9 (1C, CH=CH2) 113.6 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 55.1 (1C, CH3) 34.6 (1C, CH2CH2CH) 34.5 (1C, CH2CH2CH) IR (film): ÃŽ ½ (cm–1) 2955, 2921, 2852 (sp3 C-H Stretch), 1737, 1461(sp2 C=C Stretch), 1277, 1184, 1137 (sp3C-O Stretch), 967, 805 (sp2 C-H oop bending). HRMS (ESI) calcd. for C13H17O [M+H]+ 189.1279, found 189.1287. 2.5. Equipments 1H and 13C spectral measurements were done by using Varian NMR (400 MHz) spectrometer (model DMX 400). For protons, the chemical shifts were measured relative to tetramethylsilane (TMS) at d = 0 ppm. 3. Results and Discussion Starting material 2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3) has been synthesized as colorless oil in excellent yields (77.6%) (table 1, entry 1) by using Lithiation-Borylation methodology; Carbamate (1) was reacted with pinacol (2) by using TMEDA (2a) at suitable conditions (fig.1). Spectral studies proved the structure as mentioned in literature11. By using application of olefin cross metathesis, boronic ester (3) was then reacted with (vinylsulfonyl)benzene (4) to give (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5) as dark brown solid. Yield was again excellent (table 1, entry 2) for this reaction. Table 1: Physical states and yields Entry Substances Physical States Melting points Yield (%) 1 Colorless oil 77.60 2 Dark brown solid 82.0oC 77.25 3 Colorless oil 62.10 Boron-ate complex (6) which acted as nucleophile was synthesized by reacting (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5) with aryllithium (5a). Boron-ate complex (6) showed best nucleophilic character by using 3,5-(CF3)2C6H3Br (5a) as aryllithium11 and it was then stirred at 50oC for 1hr and then refluxed for 15hrs and desired product (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene (7) was collected. 4. Conclusions: Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene has been synthesized through a novel route and characterized by spectral techniques like IR, 1H, 13C and ms. Boron-ate complex was successfully converted into aromatic dienes. This novel synthetic route resulted in excellent yields. Acknowledgment: Authors gratefully acknowledge financial support to the work by Higher Education Commission of Pakistan and moreover authors acknowledge the Department of Chemistry, University of Engineering and Technology, Lahore-Pakistan and Superior University Lahore-Pakistan for guidance, research and laboratory facilities. References: Grubbs, R. H.; Chang, S. Tetrahedron 1998, 54, 4413–4450 Astruc D. New J. Chem., 2005, 29, 42-56. R. Larouche-Gauthier, T.G. Elford and V.K. Aggarwal, J. Am. Chem.Soc., 2011,133, 16794. Habib Hussain, Syeda Rubina Gilani, Zulfiqar Ali and Imdad Hussain, Asian Journal of Chemistry; 2013, 25, 17, 9965-9969 Hoffmann, R. W. Chem. Soc. Rev. 2003, 32, 225. Herbert C. Brown, D. Basavaiah, and N. G. Bhat, D. Basavaiah, and N. G. Bhat, J. Org. Chem. 1986, 51, 4518-4521 E. Vedejs, S. C. Fields, S. Lin, and M. R. Schrimpf, J. Org. Chem. 1995, 60, 3028-3034. Ryschkewitsch, G. E.; Garrett, J. M. J. Am. Chem. Soc. 1968, 90, 7234. Anna Bernardi, Angiolina Comotti, Cesare Gennari, Cheryl T. Hewkin, Jonathan M. Goodman, Achim Schlapbach and Ian Paterson, Tetrahedron 50, 4, 1227-1242, 1994. Bruce H. Lipshutz, Subir Ghorai, Zarko V. Boskovic, Tetrahedron, 64, 29, 2008, 6949-6954. Habib Hussain, Syeda Rubina Gilani, Zulfiqar Ali and Imdad Hussain, Asian Journal of Chemistry, In Press. [*]Corresponding Author: Habib Hussain

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â€Å"We are just an advanced breed of monkeys on a mirror planet of a very average star. But we can understand the universe. That makes us something very special†-Stephen Hawking. At the age of 21, Stephen Hawking was diagnosed with Lou Gehrig’s disease (ALS) which is a type of motor neuron disease that left him paralyzed. Hawking was given only a few years to live yet he powered through his disease. Hawking overcame this life threatening disability to become one of the most influential scientists of our modern day physics. Stephen Hawking has influenced physics by his incredible work and data explaining his revolutionary ideas evolving around black holes and their role in the universe. One of his influences to physics includes his work researching a certain type of radiation named after Hawking himself. Hawking radiation is the emission of particles of a black hole (Uehling). Hawking discovered that there are subatomic particles coming from the black hole which then releases a form of radiation. Because of Hawking’s discovery, we have learned more about how black holes can disappear. ...

Oedipus the King Essay -- Greek Tragedy Oedipus King Essays

Oedipus the King The ancient Greeks were famous for their tragedies. These dramas functioned to â€Å"ask questions about the nature of man, his position in the universe, and the powers that govern his life† (â€Å"Greek† 1). Brereton (1968) stated that tragedies typically â€Å"involved a final and impressive disaster due to an unforeseen or unrealized failure involving people who command respect and sympathy. It often entails an ironical change of fortune and usually conveys a strong impression of waste. It is always accompanied by misery and emotional distress† (20). The play, Oedipus the King, by Sophocles definitely demonstrated the characteristics of an impressive disaster unforeseen by the protagonist that involved a character of respect, included irony, and was accompanied by misery and emotional distress. Tragedies usually chronicle a disaster that was unforeseen by the protagonist. To qualify as a disaster this event must have striking circumstances (Brereton 6). The spectators of the tragedy feel a deep sympathy for the protagonist because the decision made by this character was done without intending evil (New T-349). In Oedipus the King, Oedipus chose to leave Corinth to prevent the prophecy that he would kill his father and marry his mother. Even though this appeared to be an appropriate decision, it was wrong. In the process of leaving Corinth, Oedipus came across his real father at a three-road intersection and during a scuffle killed him. Later he married his mother, Iocastà ª, fulfilling the prophecy. Oedipus did not know that this was his true father or mother because he deliberately made the decision to leave Corinth thinking that Polybos and Meropà ª were his parents. The disaster that occurred her... ...t of the play. The play spoke of the downfall of Oedipus from respected king (someone of status) to a penniless, blind, exiled peasant who was scorned by the kingdom. At the end of the play, Oedipus and his family suffered the disgrace of their true reality. Works Cited Brereton, Geoffrey. Principles of Tragedy. Florida: University of Miami Press, 1968. â€Å"Greek Tragedy.† http://www.stremnet.nf.ca/~hblake/tragedy1.html (23 Nov. 1999). â€Å"Irony.† The American Heritage Dictionary. 1969. Mandel, Oscar. A Definition of Tragedy. New York: University Press of American, 1982. Sophocles. Oedipus the King. Literature: An Introduction to Fiction, Poetry and Drama. Ed. X. J. Kennedy and Dana Gioia. 7th ed. New York: Longman, 1999. 1255-1294. â€Å"Tragedy.† New Stanford Encyclopedia. 1998. â€Å"Tragedy.† The World Book Encyclopedia. 1998.

Rasputin Essay -- Essays Papers

Rasputin Rasputin had a significant impact on the royal family as well as Russia during the reign of Czar Nicholas II. Rasputin was a staret that worked his way into the royal family. The influence of Rasputin on Alexis, the heir to the throne, gave him great power. The power given to Rasputin had a notable impact among the Russian people as well as Russia. Grigory Efimovich, better known as Rasputin, was born in the town of Pokrovskoe in 1871. The name Rasputin means "dissolute," for his tireless pursuit of girls, and "crossroads," in which his town was located between. He had a dual reputation of "second sight" from the beginning. It was said that he could spot a horse thief in a crowd with one glance and predict the weather for farmers. This cast a religious glow of sanctity about him. These were all factors that led up to him presenting himself to the Imperial Palace in 1905. Besides gaining the friendship of Grand Duchess Militza and Anastasia, Rasputin also gained the trust of Anna Vyrubova, Empress Alexandra's trusted companion. It was under the recommendation of the Grand Duchesses and Anna Vyrubova that Rasputin was summoned to appear before Alexandra. He showed up in crude country boots and a caftan. They saw that Rasputin was a very dirty man. He had a long, uncut beard, greasy hair that was slicked back, and terrible oral hygeine which is shown in the 3rd picture. Alexandra favored him and was obsessed with the man's ability to heal so he became her servant...

Uneasy Homecoming

In the short story Uneasy Homecoming written by Will F Jenkings, Connie is the first character introduced in the story, and is the protagonist; the antagonist in the short story is Mrs. Wilson and Mrs. Wilson’s son. After we are introduced to the characters we are then led into the setting, Connie was being driven home by a taxi as, â€Å"The red, dying sun cast long shadows across the road† (pg. 83), this created a picture that the sun was setting.During this cab ride home from her two week vacation, Connie feels uneasiness and dread, which help us understand the mood and atmosphere of the short story. Initiating Incident The event that begins the conflict is when Connie called Mrs. Wilson for comfort, and Mrs. Wilson ask her if her house was all right, and that it was dreadful here, there have been a series of burglaries in the town and somehow the burglary know where Mr. saddler kept his day’s receipts from his shop. Connie had a wired feeling about this and b eing alone, but she didn’t follow it because she thought it was meaningless.Rising Action Three things that are rising action is when Connie finds some cigarettes buts on the rug in Toms room and starts to panic a bit, then she finds a lump in the bed not knowing what it is she starts to walk away from it, then she look and saw it was all the burglary’s stolen stuff. Connie realized that they probably know she’s home and can see her from the bay so she turned off all the lights quickly â€Å"The window was broken. A neat jagged section of glass was missing. †(pg. 9) that’s how there were getting in, she locked all the doors and windows but not the broken one because she can’t they’ll just unlock it so she goes and hides. The climax Connie hears a noise coming from the outside garden; she knew that they knew about her knowing that they were there and had proof. They turned off the power so the house would be darker; she hears him in th e house and carefully goes out the back door, and then she lit his motorcycle on fire. â€Å"She hid herself in the shadows and watched, sobs trying to from in her throat† (pg. 91)

Asia europe transport problems

Recent political and economic developments at the global and regional levels have resulted in a more conducive development environment in the Asian and Pacific region and the opening-up of opportunities for international trade and tourism development for the developing countries of the region, including those which are landlocked. Nevertheless, the lack of unhindered access to the sea adds transport costs and time to international trade transactions. In addition, landlocked countries face greater transport risks and hazards than countries which have direct access to nternational sea routes.The United Nations has addressed the specific concerns of landlocked countries in a number of documents. Among those which are directly related to transport are the following: General Assembly resolution 50/97 of 20 December 1995 on specific actions related to the particular needs and problems of landlocked developing countries; â€Å"Global framework for transit transport cooperation between land locked and transit developing countries and the donor community† (TD/B/LDC/AC. /6); â€Å"Problem of physical infrastructure development of the landlocked countries, ncluding economies in transition† (E/ESCAP/SREC(7)/3); and â€Å"Progress report on measures designed to improve the transit transport environment in Central Asia† (A/ 51/288). With Just-in-time delivery becoming almost a prerequisite for efficient international trade, particularly in an increasingly competitive market environment, adequate attention must be given to resolving problems in transport areas which are crucial for the efficient development of the international trade of landlocked countries.The inauguration in May 1996 of a new rail line linking the Islamic Republic of Iran nd Turkmenistan, thus completing a new â€Å"silk rail route† from China to Europe via the landlocked countries of Central Asia; the priority attention of the Islamic Republic of Iran to the development of the ne cessary physical infrastructure, as well as bilateral and multilateral agreements for international transport particularly to and from Central Asia; the establishment in May 1996 of a forum for the comprehensive development of regions along the second Europe-Asia continental bridge which is of importance to Mongolia and the landlocked countries of Central Asia; the initiative of he Association of South East Asian Nations (ASEAN) on the development of a rail link from Singapore through Malaysia, Thailand, Viet Nam or the Lao People's Democratic Republic and on to Kunming, China; and the recently completed study of the South Asian Association for Regional Cooperation (SAARC) on transport and transit needs, including those of Nepal and Bhutan, are vivid illustrations of the commitment of the member countries of ESCAP to the development of a land transport network in Asia in The present note highlights some of the issues and problems of physical and soft nfrastructure in the main modes of transport (with emphasis on land transport, inland waterways and connections to seaports) which serve the landlocked countries in the region, namely Afghanistan, Armenia, Azerbaijan, Bhutan, Kazakstan, Kyrgyzstan, the Lao People's Democratic Republic, Mongolia, Nepal, Tajikistan, Turkmenistan and Uzbekistan. l.MAJOR ISSUES AND PROBLEMS IN THE TRANSPORT SECTOR To improve the efficiency and competitiveness of international trade and tourism in the landlocked countries of the region, the following issues relating to major modes of transport need to be addressed: (a) choice of alternative transit routes; b) reduction of transit costs and time along the transport routes; and (c) cooperation among the organizations concerned. A. Choice of alternative transit routes Although many of the landlocked countries in the region have several potential routes to seaports, most of them are heavily dependent on one main transit route because of limited resources and, in some cases, the limited opt ions open to them in the past as a result of the political situation at that time.This render these countries vulnerable to disruption of transit services owing to national disasters, technical and operational breakdowns, labour disputes and conflicts. Moreover, in view of regionalization and globalization of economic development, different access routes to different seaports may be required for efficient transport of goods to trade partners located in different parts of the globe. Therefore, it is important for any landlocked country to have a choice of transit land transport routes (and inland waterways if applicable) to the main seaports in Asia, as well as a choice of air transport routes and connections to major subregional, regional and global destinations. In addition, in view of the development of trade within Asia, as well as betweenAsia and Europe, there is an increasing demand for reliable and efficient intra-Asia and Asia-Europe land bridges with connections to landlocke d countries in the region. The landlocked countries need to be part of an integrated approach to the development of an intra-Asia and Asia-Europe land transport network of international importance. 1. Formalization of the international land transport network in Asia The Commission at its forty-eighth session, held in Beijing in April 1992, endorsed comprising the Asian Highway; the Trans-Asian Railway; and facilitation of land ransport, as a priority for phase II (1992-1996) of the Transport and Communications Decade for Asia and the Pacific.The objective of the project is to assist in creating a land transport network in Asia to facilitate international trade and tourism. The route selection criteria include capital-to-capital links and connections to main industrial and agricultural centres, and connections to major seaports and river ports, as well as to major container terminals and depots. The network should also provide interregional land transport linkages, particularly with the region of the Economic Commission for Europe. The project enjoys support from 25 ESCAP members, including all the landlocked countries except Armenia, Azerbaijan and Bhutan which have yet to Join the project. Armenia and Azerbaijan, however, are participating in activities that are related to ALTID.With the successful implementation of phase I (1994-1995) of the ALTID project, considerable progress has been achieved in the formulation of the international land transport network in Asia linking landlocked countries. The Asian Highway network (see figure l) has been revised in the southern corridor connecting the Islamic Republic of Iran – South Asia – South-East Asia (which includes he landlocked countries of Afghanistan, Nepal and the Lao People's Democratic Republic), and a new network formulated in the corridor South-East Asia – China – Mongolia. A study on the development of highway networks in the landlocked Asian republics (Armenia, Azerbaijan, K azakstan, Kyrgyzstan, Tajikistan, Turkmenistan and Uzbekistan) to identify the potential Asian Highway routes in those countries was completed in 1996.The Trans-Asian Railway network includes the following land bridges between Asia and Europe: Europe-Russian Federation and/or China-Korean peninsula; Europe-Islamic Republic of Iran-Central Asia-China (New Silk Railway); Europe-Islamic Republic of Iran-South Asia-South-East Asia. With the completion during phase I ofa feasibility study on connecting the rail networks of China, Kazakstan, Mongolia, the Russian Federation and the Korean peninsula, and a project on the Trans-Asian Railway in the Indo-China and ASEAN subregions, the network has been formulated in the northern corridor of the Asia-Europe routes (see fgure II) which includes the landlocked countries of Kazakstan and Mongolia, and in the Indo-China and ASEAN subregions (see figure Ill), the Lao People's Democratic Republic.A potential Trans- Asian Railway network in the sout hern corridor of the Asia-Europe routes (of importance to Afghanistan and Nepal) was also identified (see fgure ‘V) through a related preliminary study. The Commission at its fifty-second session reiterated its strong support for the ALTID project and emphasized the importance of its completion and of improving the operational efficiency of both the Asian Highway and Trans-Asian Railway networks, including the Asia-Europe links, at the earliest possible date. The Commission adopted resolution 52/9 of 24 April 1996 on Intra-Asia and Asia-Europe land bridges. rogramme of the New Delhi Action Plan on Infrastructure Development in Asia and the Pacific.It also approved the plan of action for the implementation of phase II (1996-1997) of the ALTID project, which includes a detailed study on the southern corridor of the Trans-Asian Railway, and it decided that a study on the development of the Railway in the corridor connecting South-East and North-East Asia (including the Lao People 's Democratic Republic and Mongolia) should be undertaken and that similar studies on the development of the Asian Highway and the Trans-Asian Railway in the corridor connecting northern Europe with the Russian Federation to the landlocked countries of Central Asia and the Islamic Republic of Iran should be included in the projected phase Ill (1998-1999) of the project. 13. When completed and fully operational for the whole of Asia, the land transport network could provide landlocked countries in the region with a choice of alternative land transport routes to major seaports in Asia, and land transport and land-cum-sea links to any other country in Asia and Europe.However, to realize such a potential, the landlocked countries must have unhindered access to the network. . Unhindered access to the international land transport network in Asia The construction of the regional land transport network and all related infrastructure is a necessary but not a sufficient condition for reliable and efficient international transport. A legal framework is also required to provide the basis for unhindered access to the routes for efficient international trade and tourism. A coordinated plan for the development of international land transport routes and services based on agreed performance parameters and standards is also essential.This has been vividly demonstrated by the experience of Europe, where the ollowing four major all-European transport agreements have been adopted: (a) The European Agreement on Main International Traffic Arteries (AGR Agreement) of 1975, which defines the major European roads and establishes uniform technical characteristics; (b) The European Agreement on Main International Railway Lines (AGC Agreement) of 1985, which determines the major lines and infrastructure parameters of the European railway network; (c) The European Agreement on Important International Combined Transport Lines and Related Installations (AGTC Agreement) of 1991, which is the first European ultilateral treaty governing international combined road/rail container and piggyback transport; (d)International infrastructure agreement covering European inland waterways Oanuary 1996). recommended that a legal framework should be developed for Asia in the form of ESCAP agreements on the Asian Highway and Trans-Asian Railway, taking into consideration the related experience of the European Union. With such ESCAP agreements in place, all the countries in Asia, including the landlocked countries, would enjoy free access to road and rail transport routes of international importance. 3. Inland waterways of international importance to some of the landlocked countries in Asia Inland water transport can play an important role for the regional or international trade of some landlocked countries.A number of rivers in these countries can potentially provide the cheapest means of communication with neighbouring countries, or even through them to other countries in the world. For instance, a number of tributaries of the Brahmaputra River flow out of Bhutan through India to Bangladesh; the Lao People's Democratic Republic is bordered or bisected by the Mekong River which flows through China, Myanmar, the Lao People's Democratic Republic, Thailand, Cambodia and Viet Nam; Mongolia gives rise to the Yenisey, the Angara and the Amur-Heilongjiang rivers which link the country to China and the Russian Federation; and Nepal has three of the four largest tributaries of the Ganges River flowing from India to Bangladesh.The improvement and development of inland water transport infrastructure and services would benefit all of these countries in various ways, including cost savings, environmental protection and energy savings. In addition, transit by water is more easily accepted by operators of seaports located at river mouths and it is less prone o losses, pilferage and breakage than transit by road and rail. At the present time, however, the rivers are not fully u tilized for navigation in most landlocked countries. Most of the rivers are still in a natural state without appropriate improvement and marking. Water levels in the rivers are not always regular or sufficient and the gradient is often very steep. In some river sections, the waterways are full of rapids and shoals which endanger vessel navigation or even interrupt it entirely.Some rivers are blocked with siltation, cables, pipelines, bridges, dams and other structures along or crossing them. Few aids to navigation are nstalled to mark the navigable channels in the rivers. All these factors limit the free use of the rivers for transport. However, the potential of inland water transport for international trade should be evaluated. In order to promote the use of rivers for transport which would serve the needs of landlocked countries, ESCAP is implementing several projects under the regional action programme of the New Delhi Action Plan on Infrastructure Development, which was launched by the Ministerial Conference on Infrastructure in October 1996.One of the projects is on the harmonization of requirements relating to international mportance of common or well harmonized rules, and provide guidance with regard to navigation rules, aids to navigation, the carriage of dangerous goods, facilitation measures and waterway classifications for internationally navigable rivers. Another important project is on the development of inland water transport infrastructure and services. This project includes a regional strategic study for the development of inland water transport in the ESCAP region. An intensive investigation will be carried out to identify the problems faced by the inland water transport sector. The situation ill be compared with successful experiences in other parts of the world.This study should provide a clear picture of the advantages and disadvantages of inland water transport in specific situations, identify opportunities for development and suggest regi onal actions and national policy options to expand the use of rivers for navigation in the ESCAP region. Expert group and policy-level meetings will be held to discuss the findings and suggestions of the study. Necessary follow-up actions will be taken at both the regional and national levels. With regard to some landlocked Asian republics, the same opportunity may exist or transit transport through inland waterways. Specific studies need to be carried out to identify the potential for the expanded use of inland waterways. 4. Air transport It goes without saying that reliable and efficient air transport is crucial for the economic and social progress of landlocked countries.While the emphasis in this paper is on related aspects of land transport, inland waterways and maritime linkages and transport, the following activities of the International Civil Aviation Organization (ICAO) have been included in the regional action programme 1997-2001) of the New Delhi Action Plan on Infrastruc ture Development in Asia and the Pacific and endorsed by the Ministerial Conference on Infrastructure: programme of transition to the new civil aviation communications, navigation and surveillance and air traffic management system; programme for economic reform in civil aviation in Asia and the Pacific; programme for the protection of the environment in the vicinity of airports; improvement and harmonization of flight safety standards; expansion of the UNDP-promoted ICAO TRAINAIR programme; and poverty alleviation through rural airfield development in least developed countries. These projects address major problem areas in air transport in the Asian and Pacific region, including in the landlocked countries. B.Reduction of transit time and costs along the transport routes of While the formulation of an international land transport network in Asia is in progress through the implementation of the ALTID project, there are already a provide the landlocked countries with access to seaport s. These are reflected in table 1. 1. Reduction of transit time and costs at border crossings and ports Even when all necessary infrastructure is in place, the delay of vehicles at border rossings can entail tremendous losses of resources and time. A similar problem occurs when the waiting time is long for ships to be loaded and unloaded in seaports which serve landlocked countries. When international inland waterways are available for use, delays of cargo at cross-border points have similar economic effects. a) Facilitation of land transport at border-crossings (i)Commission resolution 48/11 on road and rail transport modes in relation to facilitation measures Recognizing that harmonized transport facilitation measures are a prerequisite for efficient international trade and transport along road and rail routes of nternational importance, the Page 1 1 Commission at its forty-eighth session adopted resolution 48/11 of 23 April 1992 on road and rail transport modes in relation to fac ilitation measures. By that resolution, it recommended that the countries in the region, if they had not already done so, consider the possibility of acceding to seven international conventions. The status of the accession of the landlocked and neighbouring countries in Asia to the international conventions is shown in table 2.It is clear that in order to facilitate international and bilateral trade and tourism the constructive cooperation of the ountries is required to create a minimum legal basis for land transport cross-border traffic. In this respect ESCAP adopted a subregional approach to providing assistance to countries. A special seminar for the Economic Cooperation Organization (ECO) subregion (with the participation of Afghanistan, Azerbaijan, Kazakstan, Kyrgyzstan, Tajikistan, Turkmenistan and Uzbekistan) on the implications and benefits of accession to the conventions was held in Tehran in November 1994. A similar seminar for the North-East Asian countries (including the Lao People's Democratic Republic and Mongolia) was conducted in May 1996 in Bangkok.Another seminar for countries of the Greater Mekong subregion (including the Lao People's Democratic Republic) was organized Jointly by ESCAP and the Asian Development Bank at It is very encouraging to note that Uzbekistan has acceded to six conventions, and Kazakstan, Tajikistan and Turkmenistan have each acceded to four. However, Afghanistan, Armenia and Kyrgyzstan are each party to only two; Azerbaijan, to one; and Bhutan, the Lao People's Democratic Republic, Mongolia and Nepal to none at all. A similar situation of accession to few or no convention occurs in the neighbouring ountries of Bangladesh, Cambodia, China, India, Myanmar, Pakistan, Thailand and Viet Nam. Such a situation calls for the urgent implementation of Commission resolution 48/11 by all landlocked countries and their neighbouring countries. Transit facilitation Transit transport plays a particularly important role in the develop ment of landlocked countries.Two international conventions, namely the Convention and Statute on Freedom of Transit, Barcelona, 20 April 1921 (popularly referred to as the â€Å"Barcelona Transit Convention†), and the Convention on Transit Trade of Landlocked States, New York, 8 July 1965 (â€Å"New York Transit Convention†) assist in facilitating the transit transport of landlocked countries. However, only a few of the Asian landlocked countries and their neighbouring countries are contracting parties of these conventions, as indicated in table 3. There is clearly great potential to improve transit transport in the region. It is recommended that the landlocked countries and the neighbouring countries should accede, if they have not already done so, to the Barcelona and New York transit conventions as soon as possible.The development of a subregional multilateral transit treaty/agreement also ppears to be a promising approach to transit facilitation. Preparation of suc h a draft transit treaty for the ECO region, for example, could be carried out as part of the project on international transport development in the ECO region, which is being proposed Jointly by ESCAP, the United Nations Conference on Trade and Development and ECO for possible funding by the Islamic Development Bank. (iii) Multilateral and bilateral agreements on land transport facilitation Multilateral and bilateral agreements which govern land transport at border crossings are of great importance to the landlocked countries in Asia.Given the role f the agreements in promoting international traffic, a database covering mainland Asia is being established at ESCAP as part of the ALTID project. As indicated above, there are several main rivers in Asia which may be used by landlocked countries for international transport. To facilitate navigation and river basin development activities, a draft agreement on commercial navigation on the Lancang Jiang – Mekong River (upper reaches of the Mekong River) between the Governments of China, the Lao People's Democratic Republic, Myanmar and Thailand has been drawn up and it is expected that this agreement will be signed in the near uture.The Agreement on Cooperation for the Sustainable Development of the Mekong River Basin was signed on 5 April 1995 between the countries of the Lower Mekong River basin (Cambodia, the Lao People's Democratic Republic, Thailand and Viet Nam). The Mekong River Commission is the institutional framework through which the Agreement will be implemented. The bilateral agreement between Bangladesh and India, which is signed on a biennial basis, could also be of practical interest to landlocked countries. Similar arrangements which take into account the related experience in other regions could e of great practical value in facilitating international inland water transport in Asia, including in landlocked countries. c) Facilitation of maritime traffic In addition to facilitation for land tran sport and transport on inland waterways, facilitation of maritime traffic plays an important role in improving the efficiency of the international land-cum-sea transport systems which serve the landlocked In an era of large ships with efficient cargo operations resulting in very short stays in port, the delays caused by documentary â€Å"red tape† result in extra costs and time. To improve the situation, countries in the region having seaports (including those serving landlocked countries) are adopting the Convention on Facilitation of International Maritime Traffic, 1965 (FAL Convention) as amended. The objective of the FAL Convention is to simplify the procedures for the inward clearance of ships, cargoes, passengers and crew on arrival in a port.This can be achieved by the utilization of six standard declaration forms and the adoption of common standards for processing documentation. However, among the ESCAP members and associate members, only Australia, China, the Democra tic People's Republic of Korea, Hong Kong, Fiji, India, the Islamic Republic of Iran, the Marshall Islands, New Zealand, the Russian Federation, United States of America and Vanuatu are party (as of January 1997) to the FAL Convention. It is clear that there is potential to improve the efficiency of the land- cum-sea routes serving landlocked countries if all the coastal countries concerned accede to the FAL Convention.To assist the countries in the process of acceding to the Convention, ESCAP, in cooperation with the International Maritime Organization, ommenced in 1993 a four-year programme of country-level workshops and subregional seminars to promote the adoption of the FAL Convention and the implementation of its provisions. (d) Corridor studies To assist member countries in Asia, including landlocked countries, in the facilitation of cross-border traffic, ESCAP undertakes corridor studies to identify non- physical impediments to the flow of goods which cause delays and add unn ecessary costs to the transport process. One such study, for example, was completed in 1994 in the corridor Singapore – Malaysia – Thailand – the Lao People's Democratic Republic – Viet Nam. The study was extended in 1995 to cover Cambodia and in 1996 to include Myanmar.The study revealed the following impediments: restrictions on the movement of vehicles and drivers across borders; restrictions on the movement of cargo between the port and inland origin/destination without customs inspection in the port; restrictions on the movement of third country or transit cargo; limitations on the effective use of multimodal transport; and failure to make use of available technology and information to plan port and cargo-handling operations. The reports lso provided recommendations for dealing with these impediments. A study carried out by ADB on regional technical assistance to the Greater Mekong subregion for mitigation of non-physical barriers to cross-border mov ement of goods and people (completed in October 1996) should also be mentioned in this context.Similar studies are to be carried out as recommended by the Ministerial Conference on Infrastructure along the major intra-Asia and Asia-Europe land bridges, with the next ESCAP study planned for the corridor Port of Bandar Abbas (Islamic Republic of Iran) – landlocked countries of Central Asia – China. One other impediment frequently found in the landlocked countries in Asia is a lack of a proper coordinating mechanism at the national level among the ministries and agencies involved in cross-border procedures and formalities. 2. Improvement of transport logistics Multimodal transport, freight forwarding and electronic data interchange (ED') play an increasingly important role in the development of international trade. Just- in-time delivery, which is becoming a prerequisite for competitive international trade, increases the need for a highly efficient integrated system of de spatch, transport and

Plant and Animal Cell

First of all, plant and animal cells are eukaryotic cells. They have complex structures but they both have major differences, as well some similarities. Plant cell are usually larger than animal cell. Both types of cells have many organelles. The plant cell has a few more organelles than the animal cell but for the most part they  have the same organelles. Animal and plant cells both have a nucleus, ribosomes, Golgi apparatus, and  endoplasmic reticulum. Only plant cells have a cell wall, vacuole, chloroplast, and plastids.Both cells are controlled by a nucleus and otherwise they wouldn’t be able to function without it. As well, the ribosomes go through a process called synthesis of proteins, these proteins are necessary for life in the cells. The Golgi apparatus packs the proteins to stay in the cell. The endoplasmic reticulum is categorized into two parts, Rough endoplasmic reticulum and smooth endoplasmic reticulum. The rough endoplasmic reticulum has ribosomes attached to it; it packs the proteins made by the ribosomes.The smooth endoplasmic reticulum does not have ribosomes but it detoxifies poisonous material in the cell. Furthermore, animal cells are rounded and irregular in shape, while plant cells have fixed rectangular shapes. Plant cell have cell wall which makes a rectangular structure, these structure are composed of cellulose, hemicellulose, and a variety of other materials, but animal cells don’t have this cell wall causing it to have dynamic shapes (spherical shape).Plant cells have chloroplasts for the utilization of sunlight and this is what contributes for a plant to look green. Plant cell do photosynthesis while animal cells can’t. The chloroplast is only present in plant cell because they make their own food. Also plant cells contains a large central vacuole that is enclosed by a membrane that makes up 90% of the cell volume, while as compared to the animal cell, it has one or more vacuole but smaller that the plant cell. Also plant cell have plastids and animal cell don’t have.Plastids are small organs in the cytoplasm that stores colored pigment and food. Plant cells use linking pores in their cell wall to connect to each other and pass information while anima cells depend on an analogous system of gap-junctions that allows communication between cells. Animal cells have centrioles, cilia and lysosomes but plant cells have no need for centrioles because their spindle fibers are connected to the cell wall. Below are two pictures, one of an animal cell and the other from a plant cell.ANIMAL CELL PLANT CELL Reference: 30 Sep. 2012 http://wiki. answers. com/Q/How_do_plant_cells_differ_from_animal_cells 30 Sep. 2012 http://wiki. answers. com/Q/How_do_plant_cells_differ_from_animal_cells 30 Sep. 2012 http://scienceray. com/biology/animal-and-plant-cell-similarities-and-differences/ 30 Sep. 2012 http://www. preservearticles. com/201101032391/main-differences-between-plant-and-animal-cell. htm l 30 Sep. 2012 http://www. diffen. com/difference/Animal_Cell_vs_Plant_Cell

Charles Baudrelaire: the Swan

Main theme: Criticism of industrialization and the destruction of Paris Mode of Characterization: presented with melancholy Mood: somber, disheartened, nostalgic Tone: saddened, negative, slow, nostalgic Form: French lyric poem Alienation: The narrator, whom we assume is Baudelaire himself highlights how he was become and alien in his own city. The urban renewal and industrialization has replaced familiar sights and landmarks he had loved.The swan is a symbolically a projection f himself, like the swan he too had been taken from his native land and home. Baudelaire also plays on our understands that not only is he similar to the swan, but so too the orphans; separated from their parent's, and lost sailors and captives never to return to their true home. Allusion / Greek Mythology Baudelaire relies on the allusion to Greek mythology, with the outcome of projecting his despair at the destruction of his city.Much of the understanding of the text derives from the readers understanding of Greek mythology. The lyrical poem open with â€Å"Andromeda, I think of you! Thus Baudelaire is comparing his feelings of loss and devastation with Andromeda, who according to Greek mythology had her husband killed in the war between Troy and Greece. Not only did she had to deal with the loss of her husband in the war, but her beautiful city.Therefore Baudelaire impels via implication that he feel Just as devastated as she would, as bother their beloved cities are destroyed. Allusion / Reference to Ovid and Swan Song Baudelaire also utilizes a reference to Roman poet Ovid. Ovid wrote of the swan song which is a swan's finale gesture or effort before death. Baudelaire employs this motif o highlight his melancholy psyche that Paris is now dead, â€Å"And one old Memory like a crying horn†. Thus he reiterates his melancholy and negative feelings towards to modernization of Paris.Swan is also a symbol of purity and elegance, much like Baudelaire Paris, the swan's death and aban donment, is used to represent that Paris has been abandoned as the â€Å"silent air† indicates a lack of life. Criticism of Destruction / Development / Industrialization Imagery Bothersome, Baudelaire relies heavily on vivid imagery to demonstrate the extensive destruction particularly, the environmental destruction incurred by the arbitration. Endearing swan act as a criticism of the arbitration which would have displaced many animals and destroyed their homes.The survival of the animals seems grim as there was a â€Å"†¦ Waterless stream† which highlights the environmental damage the arbitration incurred. Baudelaire also criticisms the destruction of Paris and the urban development. He remarks â€Å"a town alas, Changes more quickly than man's heart may change† which suggests that modernity and arbitration is too fast paced for human development. Thus the reader is encouraged to mourn the loss of old Paris.

Human resources in hospitality & Marketing Hospitality Research Paper

Human resources in hospitality & Marketing Hospitality - Research Paper Example Managing human resources in hospitality is a challenging experience that requires effective planning and high level of competency (Hayes & Ninemeier, 2009). An article by Jarpi (2007) explains more about human resource in hospitality. The article explains that owners of hospitality business must be rational critical thinkers and have deep understanding on the changing rules and regulations. The author further argues that promotion of employees in the hospitality industry should be based on skills and experience. Incompetent workforce is dangerous to work with since it contributes to poor performance of the business. In this regard, effective policies should be put in place to ensure smooth operation of the workforce in an organization (Ming-chih, Haiyan & Kevin, 2011). Marketing hospitality refers to the process of selling out products and services of a hospitality firm to the target market. Marketing hospitality takes different forms, for instance; advertising, product promotion, offering of competitive prices, branding and many others.. According to Reid & Bojanic (2010), effective marketing strategies should be employed in order to boost sales and profitability in the hospitality sector. Fields (2014) wrote an article postulating various hospitality marketing strategies that can be used to boost the profits of a hospitality firm. The article states that extensive market research and establishment of realistic plans for achieving the foreseen goals and objectives of a business firm are the basic factors to success. In addition, Fields further states that, accountability is a crucial factor to consider as far as marketing hospitality is concerned. The article outlines that advertisements can be done through the print and electronic media, depending on the target market and the firm’s financial position. The modern technology has aided in providing numerous avenues for posting advertisements. For instance, the use of social media